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GCSE Chemistry · GCSEChapter 18 · Earth’s atmosphere, climate and water treatment
GCSE · Chapter 18

Earth’s atmosphere, climate and water treatment

By the end of this chapter you will be able to

  • Give the approximate composition of the atmosphere and explain its history
  • Explain the greenhouse effect and interpret data on carbon dioxide and temperature
  • Compare the sources and effects of two atmospheric pollutants
  • Describe the steps of water treatment in order
  • Compare distillation and reverse osmosis for desalination, using energy as a criterion

You should already know

  • Combustion and fuels (Chapters 12 and 15)
  • Acids and neutralisation (Chapter 10)
  • Percentages and ppm (Chapters 7 and 9)

Where this leads

  • Finite resources and recycling (Chapter 19)
  • Fertilisers and the Haber process (Chapter 14)

GCSE Chemistry. Content follows the GCSE (9-1) subject content for England (Edexcel and AQA). Content references: Describe the composition of the atmosphere and how it changed over time, Explain the greenhouse effect, global warming and the evidence for climate change, Describe atmospheric pollutants, their sources and effects, including acid rain, Describe the steps needed to make water potable, and the potable water standard, Describe desalination methods and evaluate them, including their energy use.

Exercise P  Do you remember?

1
FWhat is 0.04% of 1 000 000? Write the number in parts per million.
2
FWhich gas is produced by plants in photosynthesis? Write the name.
3
FWhat is the formula of carbon dioxide? Write the formula.
4
FWhat is the name of the gas that turns limewater milky? Write the name.
5
FWhat is 21 + 78 + 0.9? Write the number.
18.1

The composition and history of the atmosphere

GCSE
Describe the composition of the atmosphere and how it changed over time
Video lesson: The composition and history of the atmosphereComing soon
Context. A pupil asks why the air we breathe is mostly nitrogen, when we use oxygen. “Did the air always look like this?” she asks. The atmosphere has changed a great deal, and living things have changed it.

The atmosphere is about 78% nitrogen and 21% oxygen, with about 0.9% argon, a small amount of carbon dioxide (about 0.04%), and a variable amount of water vapour.

The early atmosphere had little oxygen. It was formed from gases released by volcanoes, including carbon dioxide and water vapour. Ancient cyanobacteria carried out photosynthesis and released oxygen. Much of the carbon dioxide dissolved in the oceans and was locked up in sediments such as limestone, and the oxygen level gradually rose.

GasApproximate percentage by volume
nitrogen78.0%
oxygen21.0%
argon0.9%
carbon dioxide0.04%
water vapour and other gasesabout 0.06%
Approximate composition of the atmosphere, by volume
StageWhat happened
early Earthvolcanoes released carbon dioxide, water vapour and other gases
cyanobacteriaevolved and carried out photosynthesis, releasing oxygen
oceansdissolved much of the carbon dioxide; it was locked up in sediments such as limestone
todaynitrogen and oxygen dominate; the carbon dioxide level is rising from burning fossil fuels
How the atmosphere changed

Key ideas

  • The atmosphere is about 78% nitrogen and 21% oxygen.
  • The early atmosphere was made mostly of volcanic gases; it had very little oxygen.
  • Cyanobacteria released oxygen by photosynthesis, which increased the oxygen level.
  • Carbon dioxide was locked up in the oceans and in sediments such as limestone.
Worked example 18.1.1
What percentage of the atmosphere is oxygen, approximately? Write the number.

Method. Recall the composition.

  1. Recall. About 21% of the atmosphere is oxygen.
    21
  2. Check. Check the working against the definition or table.
    checked
  3. Write the answer.
    21

Check. Nitrogen is about 78%. ✓

Worked example 18.1.2
Which organisms first released oxygen into the atmosphere? Write the name.

Method. Recall the organisms.

  1. Recall. Cyanobacteria carried out photosynthesis and released oxygen.
    cyanobacteria
  2. Decide. So the answer is cyanobacteria.
    cyanobacteria
  3. Write the answer.
    cyanobacteria

Check. They are ancient bacteria. ✓

Worked example 18.1.3
In the early atmosphere, what happened to much of the carbon dioxide? Write the words.

Method. Think about where carbon dioxide went.

  1. Look. Carbon dioxide dissolved in the oceans.
    dissolved
  2. Conclude. It was locked up in sediments such as limestone.
    limestone
  3. Write the answer.
    it dissolved in the oceans and was locked up in sediments such as limestone

Check. This reduced the carbon dioxide level. ✓

Watch out

Watch out: the atmosphere is mostly nitrogen, not oxygen. Oxygen is about a fifth of it.

Exam tip

Exam tip. Name the gas and its approximate percentage, for example “about 78% nitrogen”.

Exercise 18A  Composition and history of the atmosphere

1
FWhat is the approximate percentage of nitrogen in the atmosphere? Write the number.
2
FWhat is the approximate percentage of argon in the atmosphere? Write the number.
3
FWhat percentage of the atmosphere is carbon dioxide, approximately? Write the number.
4
FWhat gas did volcanoes release into the early atmosphere, besides water vapour? Write the name.
5
FWhich organisms first produced oxygen by photosynthesis? Write the name.
6
FWhere was much of the carbon dioxide locked up in the early atmosphere? Write the words.
7
FWhat is the approximate percentage of oxygen in the atmosphere? Write the number.
8
FDoes the atmosphere contain more nitrogen or more oxygen, by volume? Write the word.
9
PSWhat percentage of the atmosphere is about 21% oxygen, as a number of parts per 100? Write the number. (Hint: 21% of 100 parts.)
10
RExplain why the oxygen level in the atmosphere rose over time, in one sentence. Accept any sentence that says photosynthesis by cyanobacteria released oxygen into the air.
11
RExplain why the early atmosphere had little oxygen, in one sentence. Accept any sentence that says oxygen had not yet been produced in large amounts by photosynthesis.
18.2

Greenhouse gases and climate change

GCSE
Explain the greenhouse effect, global warming and the evidence for climate change
Video lesson: Greenhouse gases and climate changeComing soon
Context. A class studies a graph of carbon dioxide and temperature. “Why does a gas in the air change our temperature?” asks a pupil. Greenhouse gases absorb some of the infrared radiation that the Earth gives out, and re-emit it, which warms the lower atmosphere.

Sunlight passes through the atmosphere and warms the Earth’s surface. The Earth emits infrared radiation. Greenhouse gases, such as carbon dioxide, methane and water vapour, absorb some of this infrared and re-emit it in all directions, so the lower atmosphere and the surface are warmer than they would be otherwise. This is the greenhouse effect. The increase in greenhouse gases is causing global warming, and changes in climate.

The greenhouse effect (simplified)sunlight inatmosphere: CO<sub>2</sub>, methane and water vapourinfrared re-emittedEarth&rsquo;s surface warmssome infrared escapes to space
The greenhouse effect (simplified)
Period (approximate)Carbon dioxide (ppm, approximate)
about 1850 (before large-scale fossil fuel use)280
about 1960317
about 2000370
Approximate carbon dioxide concentration over time (rounded values)

Key ideas

  • Greenhouse gases absorb and re-emit infrared radiation from the Earth.
  • Carbon dioxide and methane are the main greenhouse gases from human activity.
  • Global warming is the increase in the average temperature of the Earth.
  • Evidence: rising carbon dioxide levels, measured over many years, and rising temperatures.
Worked example 18.2.1
Name two greenhouse gases. Write the names. Accept any two of: carbon dioxide, methane, water vapour.

Method. Recall the greenhouse gases.

  1. Recall. Carbon dioxide, methane and water vapour are greenhouse gases.
    carbon dioxide and methane
  2. Check. Check the working against the definition or table.
    checked
  3. Write the answer.
    Accept any two of: carbon dioxide, methane, water vapour.

Check. Each absorbs infrared. ✓

Worked example 18.2.2
By how much, approximately, did the carbon dioxide concentration rise from about 1850 (280 ppm) to about 2000 (370 ppm)? Write the number in ppm.

Method. Subtract the two values.

  1. Subtract. 370 - 280 = 90 ppm.
    90
  2. Check. Check the working against the definition or table.
    checked
  3. Write the answer.
    90

Check. 90 is about a third of 280. ✓

Worked example 18.2.3
Describe the greenhouse effect in one sentence. Accept any sentence that says greenhouse gases absorb infrared radiation from the Earth and re-emit it, warming the lower atmosphere.

Method. Recall the process.

  1. Recall. Greenhouse gases absorb and re-emit infrared.
    absorb and re-emit
  2. Conclude. This warms the lower atmosphere.
    warms
  3. Write the answer.
    Accept any sentence that says greenhouse gases absorb infrared radiation from the Earth and re-emit it, warming the lower atmosphere.

Check. This is a natural process that keeps the Earth warm enough. ✓

Watch out

Watch out: the greenhouse effect is natural and keeps the Earth warm. The problem is the enhanced greenhouse effect from extra greenhouse gases, which is the cause of global warming.

Exam tip

Exam tip. Link the gas, the infrared radiation and the warming in each explanation.

Exercise 18B  Greenhouse gases and climate change

1
FWhat type of radiation does the Earth emit? Write the word.
2
FWhat is the name of the warming caused by greenhouse gases? Write the name.
3
FIs methane a greenhouse gas? Write yes or no.
4
FWhat is global warming? Write the words.
5
PSIn the data, by how many ppm did carbon dioxide rise between about 1960 (317 ppm) and about 2000 (370 ppm)? Write the number.
6
FWhich is the larger value: the carbon dioxide level in about 1850 or in about 2000? Write the year as given.
7
FName the greenhouse gas that is mainly produced by burning fossil fuels. Write the formula.
8
RExplain why the greenhouse effect is necessary for life, in one sentence. Accept any sentence that says it keeps the Earth warm enough for life to exist.
9
RExplain why scientists say the rise in carbon dioxide is linked to human activity, in one sentence. Accept any sentence that says carbon dioxide has risen as fossil fuels have been burned more.
18.3

Atmospheric pollutants and acid rain

GCSE
Describe atmospheric pollutants, their sources and effects, including acid rain
Video lesson: Atmospheric pollutants and acid rainComing soon
Context. A town near a power station sees its old stone statues wearing away, and the lake nearby has few fish. “What is causing this?” asks a pupil. Sulfur dioxide and oxides of nitrogen from burning fuels dissolve in rain to make acid rain.

Burning fuels produces several pollutants. Carbon monoxide is poisonous and forms in incomplete combustion. Sulfur dioxide comes from fuels that contain sulfur, and oxides of nitrogen form at high temperatures in engines. Both dissolve in rain to form acid rain, which damages buildings, lakes and trees. Particulates (soot and dust) cause breathing problems.

Sulfur dioxide dissolves in water to form sulfurous and sulfuric acids; for example, SO2 + H2O -> H2SO3.

PollutantSourceEffect
carbon monoxideincomplete combustion of fuelspoisonous; binds to haemoglobin
sulfur dioxideburning fuels containing sulfurcauses acid rain; breathing problems
oxides of nitrogencar engines and power stationscause acid rain and smog; breathing problems
particulates (soot, dust)combustion and industrycause breathing problems and respiratory disease
Atmospheric pollutants, their sources and effects

Key ideas

  • Carbon monoxide: poisonous, from incomplete combustion.
  • Sulfur dioxide and oxides of nitrogen: cause acid rain.
  • Particulates: cause breathing problems.
  • Acid rain damages buildings, lakes and trees.
Worked example 18.3.1
Which pollutant is poisonous and forms in incomplete combustion? Write the name.

Method. Recall the pollutant.

  1. Recall. Carbon monoxide is poisonous and is formed in incomplete combustion.
    carbon monoxide
  2. Check. Check the working against the definition or table.
    checked
  3. Write the answer.
    carbon monoxide

Check. Chapter 15 covers this. ✓

Worked example 18.3.2
Name two pollutants that cause acid rain. Write the names. Accept sulfur dioxide and oxides of nitrogen.

Method. Recall the two pollutants.

  1. Recall. Sulfur dioxide and oxides of nitrogen cause acid rain.
    sulfur dioxide and oxides of nitrogen
  2. Check. Check the working against the definition or table.
    checked
  3. Write the answer.
    Accept sulfur dioxide and oxides of nitrogen.

Check. Both dissolve in rain. ✓

Worked example 18.3.3
Give one effect of acid rain on buildings. Write the words.

Method. Think about the material.

  1. Look. Acid rain reacts with the limestone or marble in buildings.
    reacts
  2. Conclude. So stone statues and buildings are worn away.
    worn away
  3. Write the answer.
    it wears away stone buildings and statues

Check. Acid rain also damages lakes and trees. ✓

Watch out

Watch out: carbon dioxide is a greenhouse gas, not the main cause of acid rain. Acid rain comes from sulfur dioxide and oxides of nitrogen.

Exam tip

Exam tip. For a pollutant, give the source, the effect and a reason, in that order.

Exercise 18C  Atmospheric pollutants and acid rain

1
FWhat is the source of sulfur dioxide in the atmosphere? Write the words.
2
FWhat is the effect of carbon monoxide on people? Write the words.
3
FWhat environmental problem is caused by sulfur dioxide and oxides of nitrogen together? Write the words.
4
FWhat pollutant causes breathing problems and is made of soot and dust? Write the name.
5
FWhat is the source of oxides of nitrogen? Write the words.
6
FDoes sulfur dioxide cause acid rain? Write yes or no.
7
PSWrite the formula of the acid formed when sulfur dioxide dissolves in water, with 3 oxygen atoms. Write the formula.
8
PSName a pollutant that is a gas, poisonous and produced by incomplete combustion. Write the formula.
9
RExplain why acid rain damages stone buildings, in one sentence. Accept any sentence that says the acid reacts with calcium carbonate in the stone.
10
RExplain why acid rain can harm fish in lakes, in one sentence. Accept any sentence that says acid rain lowers the pH of the lake, which harms fish.
18.4

Potable water

GCSE
Describe the steps needed to make water potable, and the potable water standard
Video lesson: Potable waterComing soon
Context. A town needs drinking water from a river. “Is river water safe to drink as it is?” asks the mayor. Potable water must be free from harmful microbes and have safe levels of dissolved substances, so the river water must be treated first.

Potable water is water that is safe to drink. In the UK it must meet a standard: it must not contain harmful microbes, and dissolved substances must be below safe levels. It does not need to be pure: it can contain dissolved salts and minerals that are good for health. Water treatment uses four stages: screening removes large objects; sedimentation lets solids settle out; filtration removes smaller particles through sand and gravel; and disinfection kills microbes with chlorine or ozone.

screensettlefilterdisinfectraw water in, potable (drinkable) water out
The stages of water treatment, in order

Key ideas

  • Potable water is safe to drink; it does not need to be pure.
  • Screening, sedimentation, filtration and disinfection are the four main stages.
  • Chlorine or ozone kills harmful microbes.
  • Potable water may still contain some dissolved salts.
Worked example 18.4.1
Put these in order: filtration, screening, disinfection, sedimentation. Write the first stage.

Method. Think about the order of treatment.

  1. Order. Screening removes large objects first.
    screening first
  2. Check. Check the working against the definition or table.
    checked
  3. Write the answer.
    screening

Check. Disinfection is the last stage. ✓

Worked example 18.4.2
Name a substance used to disinfect water. Write the name. Accept chlorine or ozone.

Method. Recall the disinfectant.

  1. Recall. Chlorine or ozone kills harmful microbes.
    chlorine or ozone
  2. Check. Check the working against the definition or table.
    checked
  3. Write the answer.
    Accept chlorine or ozone.

Check. Both are used in treatment works. ✓

Worked example 18.4.3
Why does potable water not need to be pure? Write the words.

Method. Think about the standard.

  1. Look. Potable water only needs to be safe to drink.
    safe
  2. Conclude. Small amounts of dissolved salts are acceptable and can be healthy.
    acceptable
  3. Write the answer.
    it only needs to be safe to drink, and dissolved salts are acceptable

Check. Pure water tastes flat and is not necessary. ✓

Watch out

Watch out: potable does not mean pure. Pure water has no dissolved substances at all; potable water has a safe level of them.

Exam tip

Exam tip. Give the four stages in order, and say what each one removes.

Exercise 18D  Potable water

1
FWhat is potable water? Write the words.
2
FWhat is the first stage of water treatment? Write the words.
3
FWhat is the name of the stage where solids settle out of the water? Write the word.
4
FWhat is the name of the stage that removes smaller particles through sand and gravel? Write the word.
5
FName one substance used to kill microbes in water. Write the name. Accept chlorine or ozone.
6
FIs it necessary for potable water to be pure? Write yes or no.
7
FWhich stage comes last in water treatment? Write the word.
8
PSPut these stages in order from first to last: disinfection, filtration, screening. Write the first one.
9
RExplain why water must be disinfected, in one sentence. Accept any sentence that says disinfection kills harmful microbes that cause disease.
10
RExplain why sedimentation is needed before filtration, in one sentence. Accept any sentence that says it removes most of the solids first, so the filter does not clog.
18.5

Desalination and the use of water

GCSE
Describe desalination methods and evaluate them, including their energy use
Video lesson: Desalination and the use of waterComing soon
Context. A coastal city has little fresh water. “Can we make the sea water drinkable?” asks a councillor. Desalination removes salt from sea water. Two methods are used, and each has a cost in energy.

Desalination makes fresh water from sea water. Distillation boils the water, and the vapour is condensed to give pure water, leaving the salt behind; it needs a lot of heat energy. Reverse osmosis forces water through a membrane that blocks the salt ions; it needs high pressure, and the membranes need maintenance. Water is also used by industry, for example for cooling and for processing, and this must be considered when water is treated.

MethodHow it worksMain drawback
distillationwater is boiled and the vapour condensed; salt is left behindneeds a lot of energy (heat)
reverse osmosiswater is forced through a membrane that blocks the salt ionsneeds high pressure, so it uses energy and needs maintenance
Two methods of desalination

Key ideas

  • Desalination: removing salt from sea water.
  • Distillation: boil and condense; needs a lot of heat energy.
  • Reverse osmosis: high pressure through a membrane; needs energy and maintenance.
  • Evaluate a method by its cost, energy use, and environmental impact.
Worked example 18.5.1
Which desalination method needs heat energy to boil the water? Write the name.

Method. Recall the method that boils water.

  1. Recall. Distillation boils the water and condenses the vapour.
    distillation
  2. Check. Check the working against the definition or table.
    checked
  3. Write the answer.
    distillation

Check. It is energy-intensive. ✓

Worked example 18.5.2
Which desalination method uses a membrane that blocks salt ions? Write the name.

Method. Recall the method with a membrane.

  1. Recall. Reverse osmosis forces water through a membrane.
    reverse osmosis
  2. Check. Check the working against the definition or table.
    checked
  3. Write the answer.
    reverse osmosis

Check. It needs high pressure. ✓

Worked example 18.5.3
Give one reason why desalination is expensive. Write the words.

Method. Think about the methods.

  1. Look. Both methods need a lot of energy, for heating or pressure.
    energy
  2. Conclude. This makes desalination costly to run.
    costly
  3. Write the answer.
    they need a lot of energy for heating or high pressure

Check. Energy costs are important in evaluation. ✓

Watch out

Watch out: a method is not good or bad on one factor alone. Evaluate desalination by its energy cost, its environmental impact (such as brine left behind) and its benefit (fresh water supply).

Exam tip

Exam tip. In an evaluation, give a benefit, a drawback, and a conclusion that weighs them.

Exercise 18E  Desalination and the use of water

1
FWhat is desalination? Write the words.
2
FIn distillation, what is condensed? Write the word.
3
FIn reverse osmosis, what does the membrane block? Write the words.
4
FWhich desalination method needs high pressure? Write the name.
5
FName the chemical substance that remains behind when sea water is distilled. Write the words.
6
PSWhich method, distillation or reverse osmosis, needs the most heat energy? Write the name.
7
FGive one environmental drawback of desalination. Write the words. Accept brine left behind, or energy use.
8
RExplain why reverse osmosis may be cheaper than distillation in some places, in one sentence. Accept any sentence that says it may use less energy overall.
9
REvaluate desalination as a source of water, in two sentences. Accept any answer that gives a benefit (a secure supply of fresh water) and a drawback (energy use or brine), with a balanced conclusion.
10
RExplain why water used by industry must be considered when a water supply is planned, in one sentence. Accept any sentence that says industry uses large volumes of water, which affects supply.

Chapter summary

SkillMethod
AtmosphereAbout 78% nitrogen, 21% oxygen, 0.9% argon, 0.04% carbon dioxide.
HistoryVolcanic gases first; cyanobacteria released oxygen; carbon dioxide dissolved and was locked up.
Greenhouse effectGreenhouse gases absorb and re-emit infrared radiation, warming the Earth.
PollutantsCarbon monoxide (poison); sulfur dioxide and oxides of nitrogen (acid rain); particulates (breathing).
Potable waterSafe to drink, not pure. Screen, settle, filter, disinfect.
DesalinationDistillation (heat) or reverse osmosis (pressure); both use energy.

Can you…?

  • I can describe the composition and history of the atmosphere
  • I can explain the greenhouse effect and interpret data on carbon dioxide
  • I can describe atmospheric pollutants, their sources and effects, and acid rain
  • I can describe the stages of water treatment in order
  • I can describe and evaluate desalination methods

Key terms

greenhouse effect
the warming of the lower atmosphere by greenhouse gases absorbing and re-emitting infrared
global warming
the increase in the average temperature of the Earth
pollutant
a substance released into the environment that causes harm
acid rain
rain made acidic by sulfur dioxide and oxides of nitrogen dissolving in it
potable water
water that is safe to drink
desalination
removing salt from sea water to make fresh water

Exercise 18Z  Check-up

1
What is the approximate percentage of nitrogen in the atmosphere? Write the number.
2
Which organisms released oxygen into the early atmosphere? Write the name.
3
Which greenhouse gas is produced by burning fossil fuels? Write the formula.
4
What is the name of the pollutant that causes acid rain together with oxides of nitrogen? Write the name.
5
What is the name of the stage in water treatment that removes large objects? Write the word.
6
Which desalination method boils sea water? Write the name.
7
What is the effect of increasing greenhouse gases on the temperature of the Earth? Write the words.
8
Explain why carbon monoxide is dangerous, in one sentence. Accept any sentence that says it is poisonous and binds to haemoglobin in the blood.
9
Explain why potable water is not pure, in one sentence. Accept any sentence that says it may contain small amounts of safe dissolved substances.

Total 24 marks. Allow about 24 minutes.

Exercise 18X  Exam-style questions

1
FName the two main gases in the atmosphere and their approximate percentages. Write two pairs.[2 marks]
2
RExplain the greenhouse effect, in two sentences. Accept any answer that says greenhouse gases absorb infrared radiation from the Earth and re-emit it, warming the atmosphere.[3 marks]
3
RDescribe the difference between carbon monoxide and carbon dioxide as pollutants, in one sentence. Accept any sentence that says carbon monoxide is poisonous, while carbon dioxide is a greenhouse gas.[2 marks]
4
FGive the four stages of water treatment in order. Write the four words.[2 marks]
5
RDescribe how acid rain forms, in two sentences. Accept any answer that says sulfur dioxide and oxides of nitrogen dissolve in rain to form acids.[3 marks]
6
RExplain why the oxygen level in the atmosphere rose, in two sentences. Accept any answer that says cyanobacteria carried out photosynthesis, releasing oxygen into the atmosphere over a long time.[3 marks]
7
REvaluate distillation and reverse osmosis as methods of desalination, in two sentences. Accept any answer that compares the energy costs: distillation needs heat, and reverse osmosis needs high pressure.[3 marks]
8
RGive one way in which a chemist would test water for pollutants, and one reason it is important. Accept any answer that says test for dissolved salts or harmful substances, to ensure it is safe to drink.[2 marks]
9
PSUse the data to state how much the carbon dioxide concentration rose between about 1850 (280 ppm) and about 2000 (370 ppm). Write the number in ppm.[2 marks]
10
RExplain why sulfur dioxide and oxides of nitrogen are more of a problem for stone buildings than for steel frames, in one sentence. Accept any sentence that says acid rain reacts with the calcium carbonate in stone.[2 marks]

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