Atomic structure and isotopes
By the end of this chapter you will be able to
- Name the parts of an atom and their relative masses and charges
- Read nuclide notation and find the numbers of particles in an atom
- Explain how the alpha scattering experiment changed the model of the atom
- Explain what isotopes are, and why they have the same chemical behaviour
- [H] Explain how energy levels account for the light given out by atoms
You should already know
- Particles in an atom: protons, neutrons and electrons (KS3 Physics or Chemistry)
- Powers of ten and standard form (KS3 Maths)
Where this leads
- Radioactivity, nuclear equations and half-life (Chapter 11)
- Nuclear fission and fusion (Chapter 12)
- The electromagnetic spectrum (Chapter 19)
GCSE Physics. Content follows the GCSE (9-1) subject content for England (Edexcel and AQA). Content references: Describe the nuclear model: a nucleus of protons and neutrons, with electrons in shells outside it, Describe how the model of the atom developed: Dalton, plum pudding, Rutherford and the alpha scattering experiment, and Bohr, Use mass number and atomic number, and nuclide notation, to find the numbers of protons, neutrons and electrons, Explain isotopes, and that they have the same number of protons but different numbers of neutrons, [H] Describe electron energy levels, and how an electron gives out a photon when it moves down a level.
Exercise P Do you remember?
Method. Multiply 10 by itself.
- Multiply. 10 x 10 = 100.10 x 10 = 100
- Write the answer. 100
Check. ✓
Method. Move the decimal point three places to the left.
- Move. 1 x 10^-3 = 1 / 1000 = 0.001.0.001
- Write the answer. 0.001
Check. ✓
Method. Recall the charges.
- Recall. Protons have a charge of +1.proton
- Write the answer. proton
Check. ✓
Method. Recall the charges.
- Recall. Neutrons have no charge.neutron
- Write the answer. neutron
Check. ✓
Method. Subtract.
- Subtract. 23 - 11 = 12.23 - 11 = 12
- Write the answer. 12
Check. ✓
The nuclear model of the atom
An atom has a small, dense nucleus at its centre, made of protons and neutrons. Electrons move around the outside of the nucleus, in shells. Almost all the mass of the atom is in the nucleus, and the atom is mostly empty space.
| Particle | Relative mass | Relative charge | Where it is |
|---|---|---|---|
| proton | 1 | +1 | nucleus |
| neutron | 1 | 0 | nucleus |
| electron | about 1/1840 | -1 | shells around the nucleus |
Key ideas
- Protons and neutrons are in the nucleus; electrons are in shells outside it.
- Protons have a charge of +1, electrons -1, and neutrons 0.
- The electron has a very small mass (about 1/1840 of a proton).
- The nucleus is about 10 000 times narrower than the whole atom (example).
Method. The mass number is the number of protons plus neutrons.
- Take the numbers. Protons = 11 and neutrons = 12.11 and 12
- Add. Mass number = 11 + 12 = 23.11 + 12 = 23
- Write the answer. 23
Check. 23 - 12 = 11 protons. ✓
Method. A neutral atom has as many electrons as protons.
- Compare. The atom is neutral, so the electrons balance the protons.balance
- Count. Electrons = protons = 11.11
- Write the answer. 11
Check. 11 protons (+11) and 11 electrons (-11) give zero charge. ✓
Method. Recall where each particle is.
- Nucleus. The nucleus contains protons and neutrons.protons, neutrons
- Outside. Electrons are in shells outside the nucleus.electrons
- Write the answer. protons and neutrons; electrons
Check. ✓
Watch out
Watch out: the nucleus holds almost all the mass but only the positive charge. The electrons carry the negative charge and the mass is very small.
Exam tip
Exam tip. Say “protons and neutrons are in the nucleus” and “electrons are in shells” exactly, as the examiners use these words.
Exercise 10A Parts of the atom
Method. Recall the uncharged particle.
- Recall. The neutron is in the nucleus and has no charge.neutron
- Write the answer. neutron
Check. ✓
Method. Recall where electrons are.
- Recall. Electrons move in shells around the nucleus.electron
- Write the answer. electron
Check. ✓
Method. Recall the charge of a proton.
- Recall. A proton has a relative charge of +1.+1
- Write the answer. +1
Check. ✓
Method. Recall the charge of an electron.
- Recall. An electron has a relative charge of -1.-1
- Write the answer. -1
Check. ✓
Method. Add the protons and the neutrons.
- Add. Mass number = 6 + 6 = 12.6 + 6 = 12
- Write the answer. 12
Check. ✓
Method. Subtract the protons from the mass number.
- Subtract. Neutrons = 16 - 8 = 8.16 - 8 = 8
- Write the answer. 8
Check. 8 + 8 = 16. ✓
Method. A neutral atom has equal numbers of protons and electrons.
- Recall. Electrons = protons = 9.9
- Write the answer. 9
Check. ✓
Method. Think about the protons and neutrons.
- Recall. Most of the mass is in the nucleus, made of protons and neutrons.nucleus
- Write the answer. nucleus
Check. ✓
Method. Subtract the atomic number from the mass number.
- Subtract. Neutrons = 39 - 19 = 20.39 - 19 = 20
- Write the answer. 20
Check. 19 + 20 = 39. ✓
Method. Add protons and neutrons.
- Add. Mass number = 15 + 16 = 31.15 + 16 = 31
- Write the answer. 31
Check. 31 - 16 = 15. ✓
Method. Think about the charges.
- Nucleus. The nucleus has positive protons.positive
- Atom. The electrons, which are negative, balance the protons in a neutral atom.balance
- Write the answer. Accept any sentence that says the protons are positive and the electrons balance them.
Check. ✓
Method. Think about where electrons are.
- Where. Electrons move in shells outside the nucleus.shells
- Protons. Protons and neutrons are the particles in the nucleus.nucleus
- Write the answer. Accept any answer that says electrons are in shells outside the nucleus.
Check. ✓
Method. The atomic number is the number of protons.
- Recall. Atomic number = number of protons = 20.20
- Write the answer. 20
Check. ✓
Method. Subtract for neutrons; electrons equal protons.
- Neutrons. Neutrons = 7 - 3 = 4.4
- Electrons. Electrons = protons = 3.3
- Write the answer. 4, 3
Check. 3 + 4 = 7. ✓
How the model of the atom developed
Dalton (early 1800s) suggested that atoms were tiny solid spheres. Thomson (about 1897) discovered electrons and suggested the plum pudding model: negative electrons spread in a positive sphere. In 1911 Rutherford and his team fired alpha particles at a thin gold foil. Most went straight through, a few were deflected, and very few bounced back. This showed that the atom has a small, dense, positive nucleus and is mostly empty space. Later, Bohr suggested that electrons move in fixed shells, or energy levels.
Key ideas
- Dalton: a solid sphere (no internal structure).
- Thomson: electrons in a positive sphere (plum pudding).
- Rutherford: a small, dense, positive nucleus; most of the atom is empty space.
- Bohr: electrons in fixed shells or energy levels.
Method. Think about what the particles passed through.
- Look. The particles passed through the foil without being deflected.straight through
- Decide. So most of the atom is empty space.empty space
- Write the answer. Most of the atom is empty space.
Check. ✓
Method. Think about what the alpha particle hit.
- Look. A few alpha particles came very close to a small, positive region.positive region
- Decide. The like charges repelled them, and the small dense nucleus caused the bounce.repelled
- Write the answer. Accept any sentence that says the particles hit a small, dense, positive nucleus.
Check. ✓
Method. Recall the model that had electrons in a positive sphere.
- Who. Thomson discovered the electron in 1897.Thomson
- Recall. Thomson discovered the electron and suggested the plum pudding model.plum pudding
- Write the answer. plum pudding
Check. ✓
Watch out
Watch out: the nuclear model did not come from one experiment alone. Rutherford’s result led to the nuclear model, and later evidence refined it.
Exam tip
Exam tip. When asked how a model changed, say what the new evidence was, and then what the new model says.
Exercise 10B The development of the atomic model
Method. Recall the first model.
- Recall. Dalton suggested the solid sphere model.Dalton
- Write the answer. Dalton
Check. ✓
Method. Recall the model.
- Recall. The plum pudding model has electrons spread in a positive sphere.plum pudding
- Write the answer. plum pudding
Check. ✓
Method. Recall the particles.
- Recall. Alpha particles were fired at the foil.alpha particles
- Write the answer. alpha particles
Check. ✓
Method. Recall the target.
- Recall. A thin gold foil was the target.gold foil
- Write the answer. gold foil
Check. ✓
Method. Recall what was observed.
- Recall. A few were deflected, and very few bounced back.a few
- Write the answer. a few
Check. ✓
Method. Think about the result.
- Recall. The nucleus is small and dense, with most of the atom empty.small
- Write the answer. small
Check. ✓
Method. Recall the scientist.
- Recall. Bohr suggested that electrons move in fixed shells or energy levels.Bohr
- Write the answer. Bohr
Check. ✓
Method. Think about the size of the nucleus.
- Look. The nucleus is very small compared with the atom.small nucleus
- Link. So most particles miss it and pass through the empty space.empty space
- Write the answer. Accept any sentence that says most of the atom is empty space.
Check. ✓
Method. Think about the evidence.
- Electrons. Electrons do exist; Thomson discovered them.exist
- Model. The model was replaced because the alpha experiment showed a small nucleus.replaced
- Write the answer. Accept any answer that says electrons were discovered, so the model was partly right but was replaced by the nuclear model.
Check. ✓
Method. Compare the old model with the new evidence.
- Evidence. Most alpha particles passed through, so the atom is mostly empty space.empty
- Result. A few deflected sharply, so the positive charge is concentrated in a small nucleus.small nucleus
- Write the answer. Accept any answer that says the atom has a small, dense, positive nucleus and is mostly empty space, not a spread-out sphere.
Check. ✓
Method. Use the dates given.
- Dates. Dalton (early 1800s), plum pudding (1897), nuclear model (1911).Dalton, 1897, 1911
- Write the answer. Dalton, plum pudding, nuclear model
Check. ✓
Method. Think about science.
- Evidence. New experiments gave results that did not fit the old model.new evidence
- Change. So the model was changed to fit all the evidence.changed
- Write the answer. Accept any sentence that says new evidence, such as the alpha scattering results, did not fit the old model.
Check. ✓
Isotopes
Isotopes are atoms of the same element, with the same number of protons (the same atomic number), but a different number of neutrons (a different mass number). Isotopes have the same chemical properties because they have the same electrons, but they can have different nuclear properties. The mass number is shown as the top number in nuclide notation: AZX, where A is the mass number, Z the atomic number and X the symbol.
| Nuclide | Mass number (top) | Atomic number (bottom) | Protons | Neutrons | Electrons (neutral) |
|---|---|---|---|---|---|
| 23Na | 23 | 11 | 11 | 12 | 11 |
| 35Cl | 35 | 17 | 17 | 18 | 17 |
| 14C | 14 | 6 | 6 | 8 | 6 |
| 4He | 4 | 2 | 2 | 2 | 2 |
| Isotope | Protons | Neutrons | Same element? |
|---|---|---|---|
| carbon-12 | 6 | 6 | yes |
| carbon-13 | 6 | 7 | yes |
| carbon-14 | 6 | 8 | yes (radioactive) |
Key ideas
- Isotopes: same protons (same element), different neutrons.
- Mass number (A) = protons + neutrons.
- Atomic number (Z) = protons.
- Neutrons = A - Z.
Method. Find the neutrons in each isotope.
- Neutrons. Chlorine-35 has 35 - 17 = 18 neutrons; chlorine-37 has 37 - 17 = 20.18 and 20
- Difference. 20 - 18 = 2 more neutrons.20 - 18 = 2
- Write the answer. 2
Check. Both have 17 protons, so they are the same element. ✓
Method. Use the atomic number of carbon.
- Recall. Carbon has atomic number 6.6
- Decide. So carbon-14 has 6 protons, the same as carbon-12.6 protons
- Write the answer. 6
Check. Carbon-14 has 14 - 6 = 8 neutrons. ✓
Method. Use neutrons = mass number - atomic number.
- Take the numbers. Mass number = 14, and atomic number of carbon = 6.14 and 6
- Subtract. Neutrons = 14 - 6 = 8.14 - 6 = 8
- Write the answer. 8
Check. 6 protons + 8 neutrons = 14. ✓
Watch out
Watch out: the isotope has the same atomic number, not the same mass number. The mass number is different for each isotope.
Exam tip
Exam tip. When asked what isotopes have in common, say “the same number of protons”, not “the same mass”.
Exercise 10C Isotopes and nuclide notation
Method. Recall the definition.
- Recall. Isotopes have the same number of protons.protons
- Write the answer. protons
Check. ✓
Method. Recall the definition.
- Recall. Isotopes have different numbers of neutrons.neutrons
- Write the answer. neutrons
Check. ✓
Method. The mass number is the top number.
- Read. Sodium-23 has a mass number of 23.23
- Write the answer. 23
Check. ✓
Method. Subtract the atomic number from the mass number.
- Subtract. Neutrons = 12 - 6 = 6.12 - 6 = 6
- Write the answer. 6
Check. ✓
Method. Subtract the atomic number from the mass number.
- Subtract. Neutrons = 13 - 6 = 7.13 - 6 = 7
- Write the answer. 7
Check. ✓
Method. Subtract.
- Subtract. Neutrons = 2 - 1 = 1.2 - 1 = 1
- Write the answer. 1
Check. ✓
Method. Same protons means the same element.
- Check. Both have 17 protons, so they are the same element, and different neutrons makes them isotopes.17 protons
- Write the answer. yes
Check. ✓
Method. Neutrons = mass number - atomic number.
- Subtract. Neutrons = 39 - 19 = 20.39 - 19 = 20
- Write the answer. 20
Check. ✓
Method. Hydrogen-2 is deuterium; hydrogen-3 is tritium.
- Deuterium. Deuterium is hydrogen-2, with mass number 2.2
- Tritium. Tritium is hydrogen-3, with mass number 3.3
- Write the answer. 2, 3
Check. ✓
Method. Think about what controls chemical reactions.
- Electrons. Chemical reactions depend on the electrons.electrons
- Same. Isotopes have the same number of electrons as each other.same electrons
- Write the answer. Accept any sentence that says they have the same number of electrons and so the same chemical properties.
Check. ✓
Method. Check the definition.
- Definition. Isotopes of an element have the same number of protons.same protons
- Element. The number of protons defines the element.defines
- Write the answer. Accept any answer that says isotopes have the same number of protons, which is what makes them the same element.
Check. ✓
Method. Subtract the neutron numbers.
- Neutrons. Carbon-12 has 6 and carbon-14 has 8 neutrons.6 and 8
- Difference. 8 - 6 = 2.8 - 6 = 2
- Write the answer. 2
Check. ✓
Method. Read the mass number and atomic number.
- Read. Mass number 12 and atomic number 6.12, 6
- Write the answer. 12, 6
Check. ✓
The size of atoms and nuclei
An atom is about 0.1 nanometres across, which is 1 x 10-10 m. The nucleus is much smaller: about 10 000 to 100 000 times narrower than the atom. Almost all the mass of an atom is in its nucleus, but almost all the volume is empty space.
Key ideas
- An atom is about 0.1 nm across: 1 x 10-10 m.
- 1 nm = 1 x 10-9 m.
- The nucleus is about 10 000 to 100 000 times narrower than the atom.
- Standard form: a number between 1 and 10 times a power of 10.
Method. Move the decimal point 10 places to the left.
- Power. 10-10 = 1 / 10 000 000 000.1 / 10^10
- Write. So the length is 0.0000000001 m.0.0000000001
- Write the answer. 0.0000000001 m
Check. ✓
Method. Divide the atom width by the nucleus width.
- Divide. (1 x 10-10) / (1 x 10-14) = 1 x 104.10^4
- Write. 104 = 10 000 times.10 000
- Write the answer. 10000
Check. Example values: an atom is 10 000 times wider than this nucleus. ✓
Method. 1 nm = 1 x 10-9 m, so multiply.
- Convert. 0.5 nm = 0.5 x 1 x 10-9 m.0.5 x 10^-9
- Standard form. 0.5 x 10-9 = 5 x 10-10 m.5 x 10^-10
- Write the answer. 5 x 10^-10 m
Check. 5 x 10^-10 = 0.0000000005 m. ✓
Watch out
Watch out: a smaller number with a larger negative power is smaller in size. 10-10 is smaller than 10-9.
Exam tip
Exam tip. When converting nanometres, multiply by 10-9. Check that your standard form number is between 1 and 10.
Exercise 10D Sizes of atoms and nuclei
Method. Recall the prefix nano.
- Recall. 1 nm = 1 x 10-9 m.10^-9
- Write the answer. 10^-9 m
Check. ✓
Method. 0.1 nm = 0.1 x 10-9 m.
- Convert. 0.1 x 10-9 = 1 x 10-10 m.1 x 10^-10
- Write the answer. 1 x 10^-10 m
Check. ✓
Method. The nucleus is inside the atom.
- Recall. The nucleus is much smaller than the atom.atom
- Write the answer. atom
Check. ✓
Method. Divide the widths: 10-10 / 10-14 = 104.
- Divide. 10-10 / 10-14 = 104.10^4
- Write the answer. 10000
Check. ✓
Method. Multiply by 10-9.
- Convert. 2 nm = 2 x 10-9 m.2 x 10^-9
- Write the answer. 2 x 10^-9 m
Check. ✓
Method. Think about the size of the particles.
- Size. The nucleus and electrons are much smaller than the whole atom.much smaller
- Result. So most of the atom is empty space, which we do not see.empty
- Write the answer. Accept any sentence that says the atoms are very small and the particles are much smaller than the atom.
Check. ✓
Method. Divide the atom width by 100 000, which is 105.
- Divide. 1 x 10-10 / 105 = 1 x 10-15 m.1 x 10^-15
- Write the answer. 1 x 10^-15 m
Check. ✓
Method. Move the point three places to the left.
- Move. 1 x 10-3 = 0.001.0.001
- Write the answer. 0.001
Check. ✓
Method. A more negative power gives a smaller number.
- Compare. -10 is more negative than -9, so 1 x 10-10 is smaller.-10 < -9
- Write the answer. 1 x 10^-10
Check. ✓
Method. Compare the two sizes.
- Sizes. The atom is about 0.1 nm across, but the nucleus is about 10 000 to 100 000 times narrower.narrower
- Write the answer. Accept any sentence that says the nucleus is much smaller than the whole atom.
Check. ✓
Electron energy levels [H]
[H] Higher tier only. Electrons can only have certain amounts of energy. These fixed amounts are called energy levels. An electron can move up a level by absorbing energy (excitation), and when it falls back down it gives out a photon of light or other electromagnetic radiation. The energy of the photon equals the difference between the two levels.
Key ideas
- [H] Electrons occupy fixed energy levels.
- [H] An electron that moves up a level must absorb energy (excitation).
- [H] An electron that falls down a level gives out a photon.
- [H] Energy of photon = difference between the two levels.
Method. The energy released is the difference between the levels.
- Subtract. Energy released = 9 - 2 = 7 units.9 - 2 = 7
- Decide. So the photon has 7 units of energy.7 units
- Write the answer. 7
Check. ✓
Method. Moving up needs energy.
- Look. The electron moves to a higher energy level.up
- Decide. Moving up means it absorbs energy.absorb
- Write the answer. absorb
Check. ✓
Method. Moving up a level needs energy.
- Look. The electron moves to a higher level, so it gains energy.up
- Calculate. The energy gained is 5 - 0 = 5 units, which is absorbed.5 - 0 = 5
- Write the answer. absorb, 5
Check. ✓
Watch out
Watch out: [H] an electron does not move gradually between levels; it jumps. The energy of the photon depends only on the two levels, not on the path.
Exam tip
Exam tip. [H] Write the energy difference first, then state whether energy is absorbed or given out.
Exercise 10E [H] Energy levels and photons
Method. Subtract the lower level from the higher.
- Subtract. 5 - 2 = 3 units.5 - 2 = 3
- Write the answer. 3
Check. ✓
Method. Subtract.
- Subtract. 9 - 5 = 4 units.9 - 5 = 4
- Write the answer. 4
Check. ✓
Method. Moving to a higher level needs energy.
- Recall. The electron gains energy, so it absorbs energy.absorb
- Write the answer. absorb
Check. ✓
Method. Recall the emitted particle or wave.
- Recall. A photon of electromagnetic radiation is given out.photon
- Write the answer. photon
Check. ✓
Method. Compare the two differences.
- First. 9 - 5 = 4 units.4
- Second. 9 - 0 = 9 units.9
- Compare. 9 is bigger than 4.9
- Write the answer. 9
Check. ✓
Method. Think about the energy levels.
- Levels. Electrons have fixed energy levels.fixed levels
- Photon. So only certain photon energies are possible.certain energies
- Write the answer. Accept any sentence that says electrons can only fall between fixed energy levels, so only certain photon energies are given out.
Check. ✓
Method. Add the two energies given out.
- First fall. 9 - 2 = 7 units.7
- Second fall. 2 - 0 = 2 units.2
- Total. 7 + 2 = 9 units, the same as one fall from 4 to 1.9
- Write the answer. 9
Check. The total energy is the same as the direct fall, 9 - 0 = 9 units. ✓
Method. Subtract the lower level from the higher.
- Subtract. 2 - 0 = 2 units.2 - 0 = 2
- Write the answer. 2 units
Check. ✓
Method. Compare the differences in energy.
- First. Level 4 to 1 is 9 - 0 = 9 units.9
- Second. Level 2 to 1 is 2 - 0 = 2 units.2
- Compare. 9 is bigger than 2.4 to 1
- Write the answer. 4 to 1
Check. ✓
Method. Moving up needs energy.
- Difference. 9 - 5 = 4 units.9 - 5 = 4
- Direction. The electron moves up, so it absorbs the energy.absorbed
- Write the answer. absorbed, 4 units
Check. ✓
Chapter summary
| Skill | Method |
|---|---|
| Nuclear model | Protons and neutrons in the nucleus; electrons in shells outside; mostly empty space |
| Development of the model | Dalton (sphere), Thomson (plum pudding), Rutherford (nucleus), Bohr (shells) |
| Numbers of particles | Protons = atomic number; neutrons = mass number - atomic number; electrons = protons when neutral |
| Isotopes | Same protons, different neutrons; same element and chemistry |
| Sizes | Atom about 0.1 nm (1 x 10^-10 m); nucleus much smaller |
| [H] Energy levels | Electrons jump between fixed levels; photon energy = difference |
Can you…?
- I can describe the nuclear model of the atom
- I can describe how the model changed, and the evidence for each change
- I can use mass number and atomic number to find the particles
- I can explain what isotopes are
- I can convert nanometres to metres in standard form
- [H] I can explain energy levels and photons
Key terms
- nucleus
- the small, dense centre of an atom, containing protons and neutrons
- mass number
- the number of protons plus neutrons in a nucleus
- atomic number
- the number of protons in a nucleus
- isotope
- atoms of the same element with the same protons and different neutrons
- alpha particle
- a positively charged particle made of two protons and two neutrons, emitted in some decays
- [H] energy level
- a fixed amount of energy an electron can have in an atom
- [H] photon
- a packet of electromagnetic radiation
Exercise 10Z Check-up
Method. Recall.
- Recall. The nucleus contains protons and neutrons.protons, neutrons
- Write the answer. protons, neutrons
Check. ✓
Method. Subtract.
- Subtract. Neutrons = 23 - 11 = 12.23 - 11 = 12
- Write the answer. 12
Check. ✓
Method. Recall the experiment.
- Recall. Rutherford’s alpha scattering experiment showed the nucleus.Rutherford
- Write the answer. Rutherford
Check. ✓
Method. Recall the result.
- Recall. Most alpha particles passed straight through the foil.passed
- Write the answer. passed
Check. ✓
Method. Recall the definition.
- Recall. Isotopes have the same number of protons and different numbers of neutrons.same protons
- Write the answer. same protons
Check. ✓
Method. Subtract.
- Subtract. 37 - 17 = 20.37 - 17 = 20
- Write the answer. 20
Check. ✓
Method. Move the point ten places left.
- Move. 1 x 10^-10 = 0.0000000001.0.0000000001
- Write the answer. 0.0000000001
Check. ✓
Method. Recall.
- Recall. The electron has a relative charge of -1.electron
- Write the answer. electron
Check. ✓
Method. Compare the models.
- Models. The plum pudding spread the positive charge through the atom.spread
- Change. The nuclear model puts it in a small nucleus.nucleus
- Write the answer. Accept any sentence that says the positive charge is in a small nucleus, not spread through the atom.
Check. ✓
Method. A neutral atom has as many electrons as protons.
- Recall. Electrons = protons = 8.8
- Write the answer. 8
Check. ✓
Total 31 marks. Allow about 31 minutes.
Exercise 10X Exam-style questions
Method. Protons from atomic number, neutrons from the difference, electrons equal protons.
- Protons. Protons = atomic number = 17.17
- Neutrons. Neutrons = 35 - 17 = 18.18
- Electrons. Electrons = 17.17
- Write the answer. 17, 18, 17
Check. ✓
Method. Describe the observation and the conclusion.
- Observation. A few alpha particles were deflected, and very few bounced back.deflected
- Conclusion. Only a small, dense, positive nucleus could push back the alpha particles.small dense nucleus
- Model. So the nuclear model replaced the plum pudding model.nuclear model
- Write the answer. Accept any answer that says a few alpha particles were deflected or bounced back, which showed a small, dense, positive nucleus.
Check. ✓
Method. Define and compare.
- Define. Isotopes are atoms of the same element with the same number of protons.same protons
- Compare. Carbon-12 has 6 neutrons and carbon-14 has 8 neutrons.6 and 8
- Difference. So carbon-14 has two more neutrons than carbon-12.two more
- Write the answer. Accept any answer that says isotopes have the same protons, and carbon-14 has two more neutrons than carbon-12.
Check. ✓
Method. Convert the atom width and divide.
- Convert. 0.1 nm = 1 x 10-10 m.1 x 10^-10
- Divide. (1 x 10-10) / (1 x 10-14) = 1 x 104.10^4
- Interpret. So the atom is about 10 000 times wider.10000
- Write the answer. 10^4
Check. ✓
Method. Use the nuclear model.
- Space. Most of the atom is empty space, so most particles miss the nucleus.empty
- Nucleus. The nucleus is small and dense, so only a few particles come close to it.few close
- Repulsion. The positive alpha particles are repelled by the positive nucleus, which deflects them.repelled
- Bounce. A very few direct hits are sent straight back.bounce back
- Write the answer. Accept any answer that says most of the atom is empty space, and a few alpha particles come close to the small, positive nucleus and are repelled.
Check. ✓
Method. Protons from the difference, then electrons.
- Protons. Atomic number = mass number - neutrons = 39 - 20 = 19.19
- Electrons. A neutral atom has 19 electrons.19
- Write the answer. 19, 19
Check. ✓
Method. Think about the levels.
- Levels. The electron can only be at fixed energy levels.fixed
- Fall. When it falls, it gives out energy equal to the difference between two levels.difference
- Photon. So the photon has a definite energy, which corresponds to one colour or wavelength.definite
- Write the answer. Accept any answer that says the energy of the photon is the difference between the two fixed energy levels.
Check. ✓
Method. Give one feature of each model.
- Dalton. Dalton: a solid sphere.solid sphere
- Thomson. Thomson: negative electrons spread in a positive sphere.plum pudding
- Rutherford. Rutherford: a small, dense, positive nucleus with empty space around it.nucleus
- Write the answer. Accept any answer that gives a solid sphere for Dalton, electrons in a positive sphere for Thomson, and a small positive nucleus for Rutherford.
Check. ✓
Method. Work out the protons, then the mass number.
- Element. Atomic number 6 is carbon, symbol C.C
- Mass number. Mass number = 6 + 8 = 14.14
- Isotope. Same number of protons (6) as carbon-12, so it is an isotope.yes
- Write the answer. C, 14, yes
Check. ✓
Method. Describe the nucleus.
- Charge. The nucleus has a positive charge from its protons.positive
- Mass. Almost all the mass of the atom is in the nucleus.mass
- Write the answer. Accept any answer that says the nucleus is positive and holds most of the mass of the atom.
Check. ✓